There are several reasons why you may not be able to have a second round of sex in one night:

1. Physical exhaustion: 
Having sex can be a physically demanding activity that can tire out your body, particularly if it's intense or lasts for a long time. After the first round, your body may need time to rest and recover before you can engage in sexual activity again.

2. Psychological factors: 
Your ability to have multiple rounds of sex may also be influenced by psychological factors such as stress, anxiety, or performance pressure. If you are feeling stressed or anxious, it may affect your ability to get and maintain an erection, or to feel sexually aroused.

3. Age: 
As men get older, their bodies may produce less testosterone, which can affect their sexual performance and stamina. This can make it harder to have multiple rounds of sex in one night.

4. Health conditions: 
Certain health conditions such as diabetes, heart disease, or high blood pressure can affect your sexual performance and ability to have multiple rounds of sex.

It's important to remember that everyone's sexual response and ability to have multiple rounds of sex can vary. If you're concerned about your sexual performance, it's a good idea to talk to your healthcare provider to rule out any underlying health conditions and to discuss strategies for improving your sexual function.